câu 1

a) CuO+H2SO4-->CuSO4 + H2O

\(m_{h2so4}=196.5\%=9.6\left(g\right)\)

\(n_{h2so4}=\dfrac{9.8}{98}=0.1\left(mol\right)\)

\(n_{CuO}=n_{h2SO4}=0.1\left(mol\right)\)

\(m_{CuO}=80\cdot0,1=8\left(g\right)\)

b)

\(m_{CuSO4}=160\cdot0,1=16\left(g\right)\)

\(m_{ddCuSO4}=8+196=204\left(g\right)\)

\(C\%_{MgSO4}=\dfrac{16}{204}\cdot100\%=7,84\%\)

c)\(n_{MgO}=n_{H2SO4}=0.1\left(mol\right)\)

\(m_{MgO}=n\cdot M=0.1\cdot40=4\left(g\right)\)

2/

MgO+ 2HCl ----> MgCl₂+ H₂O

n_MgCl2=0.2 mol

a)Theo pt n_MgO=n_MgCl2=0.2 mol

=> m_MgO=40*0.2=8 g

b) Theo pt n_HCl=2n_MgCl2=0.4 mol

Mà dd có nồng độ 10%

=>V_HCl=\(\dfrac{0.4\cdot36.5\cdot100}{1.2\cdot10}\approx121.67ml\) (V=m/D)

a, \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

b, \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)

Theo PT: \(n_{CuO}=n_{CuCl_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\)

\(\Rightarrow m_{CuO}=0,05.80=4\left(g\right)\)

c, \(C_{M_{CuCl_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)

PTHH :

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

0,05         0,1         0,05

\(b,m_{CuO}=0,05.80=4\left(g\right)\)

\(c,C_{M\left(CuCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(n_{CuO}=\dfrac{32}{80}=0,4(mol)\\ CuO+2HCl\to CuCl_2+H_2\\ \Rightarrow n_{HCl}=0,8(mol);n_{CuCl_2}=n_{H_2}=0,4(mol)\\ a,m_{dd_{HCl}}=\dfrac{0,8.36,5}{20\%}=146(g)\\ b,m_{CuCl_2}=0,4.135=54(g)\\ c,C\%_{CuCl_2}=\dfrac{54}{32+146-0,4.2}.100\%=30,47\%\)

\(CuO + 2HCl \rightarrow CuCl_2 + H_2O\)

\(n_{CuO}= \dfrac{32}{80}= 0,4 mol\)

Theo PTHH:

\(n_{HCl}= 2n_{CuO}= 0,8 mol\)

\(\Rightarrow m_{HCl}= 0,8 . 36,5=29,2 g\)

\(\rightarrow m_{dd HCl}= \dfrac{29,2 . 100%}{20%}= 146 g\)

b) Muối tạo thành là CuCl₂

Theo PTHH:

\(n_{CuCl_2}= n_{CuO}= 0,4 mol\)

\(\Rightarrow m_{CuCl_2}= 0,4 . 135= 54g\)

c)

\(m_{dd sau pư}= m_{CuO} + m_{dd HCl}= 32 + 146=178 g\)

C%= \(\dfrac{54}{178} . 100\)%= 30,337 %

\(-\) \(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)

\(pt:CuO+2HCl\rightarrow CUCl_2+H_2O\)

 \(a,\) 

\(-\) \(n_{HCl}=2.n_{CuO}=2.0,4=0,8\left(mol\right)\)

\(\rightarrow\) \(m_{HCl}=0,8.36,5=29,2\left(gam\right)\)

\(\Rightarrow\) \(m_{ddHCl}=29,2:20\%=146\left(gam\right)\)

\(b,\)

\(-\) \(n_{CuCl_2}=n_{CuO}=0,4\left(mol\right)\)

\(\rightarrow\) \(m_{CuCl_2}=0,4.135=54\left(gam\right)\)

\(c,\)

\(m_{ddsaupu}=32+146=178\left(gam\right)\)

\(\Rightarrow\) \(C\%_{CuCl_2}=\dfrac{54}{178}.100\%=30,34\%\)

\(n_{CuO}=\dfrac{1.6}{80}=0.02\left(mol\right)\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(0.02.......0.02.................0.02\)

\(m_{H_2SO_4}=0.02\cdot98=1.96\left(g\right)\)

\(m_{dd_{H_2SO_4}}=\dfrac{1.96}{20\%}=9.8\left(g\right)\)

\(m_{\text{dung dịch sau phản ứng }}=1.6+9.8=11.4\left(g\right)\)

\(C\%_{CuSO_4}=\dfrac{0.02\cdot160}{11.4}=28.07\%\)

nHCl=0,3.2=0,6(mol)

a) PTHH: CuO +2 HCl -> CuCl2 + H2O

0,3_______________0,6___0,3(mol)

b) mCuO=0,3.80=24(g)

c) VddCuCl2=VddHCl=0,3(l)

=>CMddCuCl2=0,3/0,3=1(M)

d) m(muối)=0,3.135=40,5(g)